with cte as
(
   select *, 
      row_number() over (partition by EmpId order by Intime) as row_Id
   from YourTable
)
select 
    EmpId,
    max(case when row_id = 1 then Intime end) as FirstIntime,
    max(case when row_id = 1 then Outtime end) as FirstOuttime,
    max(case when row_id = 2 then Intime end) as FirstIntime,
    max(case when row_id = 2 then Outtime end) as FirstOuttime
from
	cte
group by 
	empId
order by
	EmpId

SELECT EmpID,
       MAX(CASE WHEN rnk = 1 THEN CONVERT(VARCHAR(8), Intime, 108) END) AS [1inTime],
       MAX(CASE WHEN rnk = 1 THEN CONVERT(VARCHAR(8), OutTime, 108) END) AS [1outTime],
       MAX(CASE WHEN rnk = 2 THEN CONVERT(VARCHAR(8), Intime, 108) END) AS [2inTime],
       MAX(CASE WHEN rnk = 2 THEN CONVERT(VARCHAR(8), OutTime, 108) END) AS [2outTime]
  FROM (
         SELECT *, ROW_NUMBER() OVER(PARTITION BY EmpID
                                     ORDER BY Date ASC) AS rnk
           FROM TableName
       ) AS D
 GROUP BY EmpID
 ORDER BY EmpID;